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For solid state NMR: What can cause the line position shift depending on the spin rate?

asked Jun 21 '10 at 01:56

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KateSTR
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The isotropic chemical shift is independent of spinrate. Spin Sidebands are located at a n*spinrate(n=1,2,3...) distance with respect to isotropic peaks.

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answered Jun 21 '10 at 18:52

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Frey
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Maybe shift changes as result of imperfect temperature control? The faster you spin the more you may end up heating the sample.

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answered Jun 21 '10 at 19:12

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Evgeny Fadeev
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Asked: Jun 21 '10 at 01:56

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Last updated: Jun 21 '10 at 19:12

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