Chemical shift and spin rate

1	For solid state NMR: What can cause the line position shift depending on the spin rate? line position spin rate asked Jun 21 '10 at 01:56 KateSTR 11

2 Answers:

oldest newest most voted

1	The isotropic chemical shift is independent of spinrate. Spin Sidebands are located at a nspinrate(n=1,2,3...) distance with respect to isotropic peaks. link answered Jun 21 '10 at 18:52* Frey 61

0	Maybe shift changes as result of imperfect temperature control? The faster you spin the more you may end up heating the sample. link answered Jun 21 '10 at 19:12 Evgeny Fadeev 577●1

Here (once you log in) you will be able to sign up for the periodic email updates about this question.

Your answer

Please start posting your answer anonymously - your answer will be saved within the current session and published after you log in or create a new account. Please try to give a good answer, for discussions, please use comments and please do remember to vote (login to vote)

toggle preview

Tags:

spin ×4
line ×2
position ×1
rate ×1

Asked: Jun 21 '10 at 01:56

Seen: 5,103 times

Last updated: Jun 21 '10 at 19:12

Related questions