Dear sirs I have a natural product whose two carbon resoances are appearinga t 46 and 56 ppm but theirs proton resoanances are appearinga at 0.80 and 0.83 ppm respectively. I am unable to understand how there could be a downfield carbon (oxygenated carbon) is paird up with a upfield proton. I request your expert answer. Thanks in advance.

Dear sirs sirs and madams, I have a natural product whose two carbon resoances are appearinga t appearing at 46 and 56 ppm but theirs proton resoanances are appearinga appearing at 0.80 and 0.83 ppm respectively. I am unable to understand how there could be a downfield carbon (oxygenated carbon) is paird up with a upfield proton. I request your expert answer. Thanks in advance.